Access to Unsymmetrically Substituted Diaryl Gold N‐Acyclic Carbene (NAC) and N‐Heterocyclic Carbene (NHC) Complexes via the Isonitrile Route
نویسندگان
چکیده
Abstract A variety of unsymmetric diaryl gold N‐acyclic c arbene (NAC) complexes was synthesized via the isonitrile route by three different methods: (a) solvent free in a melt, (b) mechanochemically and (c) THF at room temperature. The latter method can also be used to synthesize unsaturated NHC complexes. These methods overall offer access broad array new remove one previous limitations NAC gold, namely inability react with less nucleophilic aromatic amines. proved successful as pre‐catalysts gold‐catalyzed phenol synthesis. magnified image
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ژورنال
عنوان ژورنال: Advanced Synthesis & Catalysis
سال: 2021
ISSN: ['1615-4169', '1615-4150']
DOI: https://doi.org/10.1002/adsc.202101000